Comparison of Handheld and Echelle Spectrometer to Assess Copper in Ores by Means of Laser-Induced Breakdown Spectroscopy (LIBS)
نویسندگان
چکیده
Its properties make copper one of the world’s most important functional metals. Numerous megatrends are increasing demand for copper. This requires prospection and exploration new deposits, as well monitoring quality in various production steps. A promising technique to perform these tasks is Laser Induced Breakdown Spectroscopy (LIBS). unique feature, among others, ability measure on site without sample collection preparation. In this work, copper-bearing minerals from two different deposits studied. The first set field samples come a volcanogenic massive sulfide (VMS) deposit, second part stratiform sedimentary (SSC) deposit. Different approaches used analyze data. First, univariate regression (UVR) used. However, due strong influence matrix effects, not suitable quantitative analysis grades. Second, multivariate method partial least squares (PLSR) used, which more quantification. addition, effects surrounding matrices LIBS data characterized by principal component (PCA), alternative methods PLSR tested calibration validated using samples.
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ژورنال
عنوان ژورنال: Minerals
سال: 2023
ISSN: ['2075-163X']
DOI: https://doi.org/10.3390/min13010113